Simultaneous Coproduction of Xylonic Acid and Xylitol: Leveraging In Situ Hydrogen Generation and Utilization from Xylose.

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Tác giả: Ali Awad, Ji Hoon Kim, Jaehoon Jung, Young Kyu Hwang, Ajaysing S Nimbalkar, Kyung-Ryul Oh, Fajar Prihatno, Pravin P Upare, Anil H Valekar

Ngôn ngữ: eng

Ký hiệu phân loại: 345.0522 Criminal law

Thông tin xuất bản: Germany : ChemSusChem , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 736685

Pentose oxidation and reduction, processes yielding value-added sugar-derived acids and alcohols, typically involve separate procedures necessitating distinct reaction conditions. In this study, a novel one-pot reaction for the concurrent production of xylonic acid and xylitol from xylose is proposed. This reaction was executed at ambient temperature in the presence of a base, eliminating the need for external gases, by leveraging Pt-supported catalysts. Initial experiments using commercially available metal-supported carbon catalysts validated the superior activity of Pt. However, a notable decline in recycling performance was observed in Pt/C, which is attributed to the sintering of Pt nanoparticles. In contrast, the synthesized Pt-supported ZrO
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