Stabilization of Alkyltin γ-Keggin Clusters by 2, 5-Dihydroxyterephthalate Ligands.

• Tác giả: Wei-Hui Fang, Dong-Sheng Li, Peng Li, Qian Zhou, Yu Zhu
• Ngôn ngữ: eng
• Thông tin xuất bản: Germany : Chemistry, an Asian journal , 2025
• Bộ sưu tập: NCBI
• ID: 737129

Tóm tắt

The Keggin clusters are one kind of the most representative molecular structures in the field of metal-oxo clusters. Although the different types of Keggin clusters with various components were reported, the research about γ-Keggin isomer remains less developed. This is ascribed to the difficulty in obtaining the stable pure γ-Keggin cluster for the structural isomerization. In this study, we adopted a ligand stabilization strategy to get the stable pure γ-Keggin structure [(n-BuSn)