In Situ Electron Paramagnetic Resonance Investigation of Isotope-Selective Breathing in MIL-53 During Dihydrogen Adsorption.

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Tác giả: Volodymyr Bon, Sibo Chetry, Muhammad Fernadi Lukman, Michael Hirscher, Stefan Kaskel, Harald Krautscheid, Andreas Pöppl, Prantik Sarkar, Kavipriya Thangavel

Ngôn ngữ: eng

Ký hiệu phân loại: 538.364 Electron paramagnetic resonance (EPR)

Thông tin xuất bản: Germany : Chemistry (Weinheim an der Bergstrasse, Germany) , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 737323

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The development of smart materials capable of separating dihydrogen isotopologues has risen recently. Among potential candidates, the flexible MIL-53 (Al) has been gaining attention due to its structural flexibility providing the so-called ''breathing mechanism'' that can be useful to separate hydrogen isotopologues selectively. In the present work, an in situ continuous wave electron paramagnetic resonance investigation has been proven as a sensitive technique to follow the isotopologue-selective adsorption-desorption of dihydrogen species on the paramagnetic metal-doped MIL-53 (Al

1. In
2. Situ
3. Electron

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