Carbonaceous materials have attracted extensive research and application interests in water treatment owing to their advantageous structural and physicochemical properties. Despite the significant interest and ongoing debates on the mechanisms through which carbonaceous materials facilitate advanced oxidation processes (AOPs), a systematic summary of carbon materials across all dimensions (0D-3D nanocarbon to bulk carbon) in various AOP systems remains absent. Addressing this gap, the current review presents a comprehensive analysis of various carbon/oxidant systems, exploring carbon quantum dots (0D), nanodiamonds (0D), carbon nanotubes (1D), graphene derivatives (2D), nanoporous carbon (3D), and biochar (bulk 3D), across different oxidant systems: persulfates (peroxymonosulfate/peroxydisulfate), ozone, hydrogen peroxide, and high-valent metals (Mn(VII)/Fe(VI)). Our discussion is anchored on the identification of active sites and elucidation of catalytic mechanisms, spanning both radical and nonradical pathways. By dissecting catalysis-related factors such as sp