Fluorescence of Helical Molecular Springs Under High Pressure.

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Tác giả: Katrin Amann-Winkel, Weizhao Cai, Tobias Eklund, Cheng-Wei Ju, Aigerim Karina, Hailong Li, Jiaxu Liang, Zonghang Liu, Klaus Müllen, Zijie Qiu, Manfred Wagner, Tanja Weil, Wenhao Zheng

Ngôn ngữ: eng

Ký hiệu phân loại: 573.97 *Electric organs

Thông tin xuất bản: Germany : Angewandte Chemie (International ed. in English) , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 742167

Although the unique structure of helicenes resembles molecular springs, the effects of their extension-contraction cycles on their properties have rarely been explored. Here, we investigated the fluorescence of two π-extended [n]helicenes with different helical lengths n, named [7] and [9], under high pressures in a diamond anvil cell. The experimental results showed that compound [9], with a longer helical length, exhibited a more sensitive fluorescence response than [7] in both crystalline and solvated states upon compression. Theoretical calculations reveal that π-π overlapping at their helices in these molecular springs provides an additional contribution to their fluorescence properties under compression when the overlap becomes sufficiently strong. Our results provide insights into structure-property relationships of helical molecules under high-pressure conditions and verify the potential of helicenes as molecular springs for future applications in molecular machines.
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