Sodium-organic batteries (SOBs) are widely recognized as a rising star in large-scale energy storage technology because of their abundant resources, high energy density, and environmental friendliness. However, the poor cyclability and rate performance due to high solubility and poor conductivity with organic electrode materials limit their practical applications. Here, we constructed a new crystalline polymer, poly(tetraaminobenzoquione) (PTABQ), featuring a layered structure with a conjugated backbone and intermolecular hydrogen bonds. Benefiting from the crystalline structure with one-dimensional O-channels and highly conjugated backbone, PTABQ shows high electronic conductivity (10