Enhancement of Uranium Ionization Efficiencies Using Zn-MOF-74 Derived Nanoporous Ion Emitters for Thermal Ionization Mass Spectrometry.

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Tác giả: Dushyant Barpaga, Eirik J Krogstad, Abhishek Kumar, Kyle A Makovsky, Kelly McHugh, Ji-Hye Seo, Michael A Sinnwell

Ngôn ngữ: eng

Ký hiệu phân loại: 948.5038 *Sweden

Thông tin xuất bản: United States : Analytical chemistry , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 744126

The recent introduction of nanoporous ion emitters (nano-PIEs) formed from metal-organic frameworks (MOFs) has demonstrated their potential to enhance sensitivity for thermal ionization mass spectrometry (TIMS). Nano-PIEs take advantage of the parent MOF's chemical and structural tunability to form scaffolds for ion emitters. A study by Barpaga et al., 2023 on MOF-74 as the parent material found that with high volatility metals in their framework, uranium sample utilization efficiency (SUE) increases by up to 9-fold (e.g., Zn-MOF-74) compared to that of the analyte on a bare filament (∼0.05%). In this study, we investigate the performance of Zn-MOF-74 to maximize uranium efficiencies at the trace level (= 10
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