Preparation of electrochemical aptamer-based sensors: a direct aryl diazonium grafting approach.

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Tác giả: Tony Breton, Liam R Carroll, Essam M Dief, J Justin Gooding, Wenxian Tang

Ngôn ngữ: eng

Ký hiệu phân loại: 973.332 Operations of 1776-January 3, 1777

Thông tin xuất bản: England : Chemical communications (Cambridge, England) , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 744160

Electrochemical aptamer-based (EAB) sensors represent a promising platform for continuous monitoring of a wide range of biomarkers due to the unique properties of aptamers, such as high affinity, target binding reversibility and ease of designing them for a desired target analyte. Currently, the performance of EAB sensors is limited by the instability of the molecule/electrode link that is mostly based on the gold-sulphur semi-covalent bonds that can be chemically and electrochemically unstable during operation of an EAB sensor. In this work, we introduce, for the first time, an aryl diazonium salt-derived covalent surface chemistry that enables the direct grafting of aptamers on gold electrodes, in a single step, by the spontaneous reduction of an
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