Synergistic regulation of metal-organic cage architectures via temperature- and solvent-driven atropisomerism.

• Tác giả: Qian-Nan Bi, Xu-Lang Chen, Jie Cui, Han-Yuan Gong, Ai-Jiao Guan, Xiang Hao, Qian Li, Xiaopeng Li, Zhi-Ao Li, Jiaqi Liang, Tong-Ling Liang, Li-Jun Peng, Heng Wang, Yu-Dong Yang, Ke-Lin Zhu
• Ngôn ngữ: eng
• Ký hiệu phân loại: 636.7533 Dogs
• Thông tin xuất bản: United States : Proceedings of the National Academy of Sciences of the United States of America , 2025
• Bộ sưu tập: NCBI
• ID: 745460

Tóm tắt

Regulating multistimulus responses in artificial systems remains a challenge in smart material development. We present a versatile chemical switching system that precisely controls the self-assembly of metal-organic cages via temperature and solvent changes. The key component, cyclo[2](1,3-(4,6-dimethyl)benzene) (4-pyridine)[6](1,3-(4,6-dimethyl)benzene) (