Hydroponic farming is gaining importance due to the rapid expansion of cities worldwide. However, the significance of nano-enabled nutrient delivery in hydroponic crop culture is still poorly understood. Therefore, ZnO monometallic and Zn-Cu bimetallic nanoparticles (MNP and BNP) were innovatively synthesized through green routes using alcoholic leaf extract (ALE) 1-10 % (w/v) of Chrysalidocarpus lutescens due to its enriched phytochemical profile, prolific radical scavenging efficiency, and reasonably high IC50 values. The structural uniformity and batch-wise yield of MNP and BNP were optimized following response surface methodology. The uniqueness of C. lutescens-derived phytochemicals facilitated the production of anisotropic and crystalline MNP and BNP. It was revealed that structural uniformity and yields were most significant at pH 9 with 3 % ALE for both MNP (Yield/batch -20.54 ± 0.15 g) and BNP (Yield/batch - 18.37 ± 0.30 g). Both nanoparticles were hexagonal 30-85 nm nanocrystals, stable at alkaline pH (∼9) with uniform pore volume, surface area, and surface charge. The hydroponic compatibility of the MNP and BNP were compared with non-nanoscale Zn and Cu by cultivating Cicer arietinum with different doses of MNP, BNP, and other treatments. Among all doses, 250 and 500 mg L