Chiral Diazatriptycene Exhibiting Acid-Induced Ternary Circularly Polarized Luminescence Switching and Crystal Morphology Changes.

• Tác giả: Tomohiro Agou, Atsushi Aoki, Ryo Inoue, Yasuhiro Morisaki
• Ngôn ngữ: eng
• Ký hiệu phân loại: 663.13 Fermentation
• Thông tin xuất bản: Germany : Angewandte Chemie (International ed. in English) , 2025
• Bộ sưu tập: NCBI
• ID: 745675

Tóm tắt

Doubly N-doped triptycene 2,6-diazatriptycene 1 was synthesized as the first example of triptycene-bearing intrinsic chirality in its core. The resolved enantiomers exhibited an acid-induced ternary circularly polarized luminescence (CPL) switching behavior, enabling on/off and +/- control, with a dissymmetry factor (g