High-entropy alloys (HEAs), composed of five or more elements in similar proportions, exhibit unique physicochemical properties, but their disordered atomic structures pose challenges in the precise control of active sites. In contrast, high-entropy intermetallic compounds (HEIs), with an ordered atomic arrangement and well-defined atomic positions, provide clear active site configurations, making them particularly advantageous for complex electrocatalytic reactions like the nitrate reduction reaction (NO