Molecular and Descriptor Spaces for Predicting Initial Rate of Catalytic Homogeneous Quinoline Hydrogenation with Ru, Rh, Os, and Ir Catalysts.

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Tác giả: Néstor Cubillan, Rodolfo Izquierdo, Yovani Marrero-Ponce, Merlín Rosales, Rafael Zadorosny

Ngôn ngữ: eng

Ký hiệu phân loại: 523.019 Molecular, atomic, nuclear physics

Thông tin xuất bản: United States : ACS omega , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 747018

Developing highly active catalysts for quinoline hydrogenation is crucial for efficient hydrogen carrier technologies and clean fossil fuel hydrodenitrogenation. In this work, we employed Tensor Algebra-based 3D-Geometrical Molecular Descriptors (QuBiLS-MIDAS) to develop Quantitative Structure-Property Relationship (QSPR) models predicting the initial rate of homogeneous quinoline hydrogenation catalyzed by transition metal complexes of Ru, Rh, Os, and Ir. A data set of 32 catalytic precursors was used: 25 for model training (training set) and 7 for external validation (testing set). Multiple linear regression analysis yielded a model with good predictive ability for the training set (
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