Pain and suffering are physical and psychological sensations that affect people throughout life. In those who witness the suffering of others, various types of emotions may arise, making them feel connected to those who are suffering with different intensity. It is important to examine which emotion brings them closer to the pain of others, because depending on which one is predominant the therapeutic and intersubjective relationship of accompaniment and help can be facilitated or interrupted. Here, we examine the different emotions that arise in the presence of suffering individuals: sorrow, pity, empathy, commiseration, compassion, and finally mercy and transcendence, and the differences among them based on interpersonal proximity.