Development and validation of an environmentally friendly fluorescence quenching method for linagliptin quantification using eosin Y: optimization

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Tác giả: Adel Al Fatease, Ahmed A Almrasy, Ali Alqahtani, Saud Alqahtani, Taha Alqahtani

Ngôn ngữ: eng

Ký hiệu phân loại: 338.9 Economic development and growth

Thông tin xuất bản: England : RSC advances , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 748002

Diabetes management has increasingly relied on dipeptidyl peptidase-4 inhibitors like linagliptin, creating a need for environmentally sustainable analytical methods to replace conventional chromatographic techniques that often involve complex sample preparation, organic solvent usage, and expensive instrumentation. A sensitive and selective "turn-off" fluorescence quenching method was developed and validated for the determination of linagliptin using eosin Y as the fluorescent probe. The spectral characteristics and sensing mechanisms were investigated using Stern-Volmer analysis, Job's method, and thermodynamic studies, revealing a static quenching process driven by the formation of a non-fluorescent 1 : 1 linagliptin-eosin Y complex with a high Stern-Volmer constant (
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