Electrochemical dearomatization of 2-naphthols for C-O bond formation.

• Tác giả: Dong Kyun Han, Seo-Jung Han, Han Byeol Kim, Jae Kyun Lee
• Ngôn ngữ: eng
• Ký hiệu phân loại: 296.1146 Sources
• Thông tin xuất bản: England : RSC advances , 2025
• Bộ sưu tập: NCBI
• ID: 748016
• Chủ đề: 1. Electrochemical; 2. Dearomatization; 3. Of

Tóm tắt

We reported a metal-free electrochemical oxidative C-O homocoupling of 2-naphthols, followed by subsequent alkoxylation under mild conditions. This strategy offered an eco-friendly and cost-effective electrochemical approach using undivided cells. Additionally, the reaction exhibited broad tolerance to various substituted 2-naphthols and diverse alcohols, affording the corresponding naphthalenones in moderate to good yields.