Atomistic Electrocatalysts for Modulating the Oxygen Reduction Reaction Selectivity in Carbon-Based Materials: Active-Site Engineering, Local Environment, and Magnetism.

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Tác giả: Jonathan Guerrero-Sanchez, Jose Manuel Romo-Herrera

Ngôn ngữ: eng

Ký hiệu phân loại: 398.357 Artistic and literary themes

Thông tin xuất bản: United States : ACS materials Au , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 748188

The oxygen reduction reaction (ORR) is an electrochemical process that is key to tackling global concerns regarding the conversion and storage of clean energy as well as the development of sustainable water treatment. We mainly focus on nonprecious metal catalysts, specifically harnessing Carbon-based electrocatalysts. In the current invited perspective, we highlight three main ways to control the ORR selectivity, which is still a challenge under development: (i) engineering the active sites where the use of single-atom, double-atom, or small clusters of atoms of transition metals in the carbon matrix allow including more active sites for the reaction, (ii) using coordination shells and modifying the local environment of the active-sites with more electronegative elements generates a strong positive electrostatic potential in the active site thus improving the metal-O
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