Borinine-FLP ring expansion: isolation of eight-membered B-P rings bridged by μ

• Tác giả: Diane A Dickie, Nathan C Frey, Robert J Gilliard, Andrew Molino, Samir Kumar Sarkar
• Ngôn ngữ: eng
• Ký hiệu phân loại: 573.798 *Flying
• Thông tin xuất bản: England : Chemical science , 2025
• Bộ sưu tập: NCBI
• ID: 748663

Tóm tắt

Boron-phosphorus (B-P) frustrated Lewis pairs (FLPs) are an important class of compounds for activating various small molecules. Utilizing the ring expansion reactivity of 9-chloro-9-borafluorene, a borinine-based FLP was synthesized. Various five-membered main-group element heterocycles were obtained