Sliding ferroelectricity in bilayer phosphorus analogue compounds: mechanisms and applications.

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Tác giả: Xin-Yi Gao, Zeng-Yun Gu, Yan-Dong Guo, Yu-Ting Guo, Zhi-Peng Huan, Yue Jiang, Li-Yan Lin, Dong-Dong Wang, Xiao-Hong Yan, Hong-Li Zeng

Ngôn ngữ: eng

Ký hiệu phân loại: 338.8891 Combinations

Thông tin xuất bản: England : Nanoscale , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 749861

 Two-dimensional (2D) van der Waals (vdW) ferroelectric structures have attracted much attention due to their superior properties and broad application prospects. For many systems, although there have been plenty of studies on monolayer ferroelectrics, bilayer or multilayer ferroelectricity has been rarely investigated. Here, we focus on the sliding ferroelectricity of bilayer α- and β-phase MX (M = Si, Ge, Sn and Pb
  X = S, Se and Te) structures. Bilayer α-SiS is found to exhibit a quite large out-of-plane polarization that is not present in the monolayer configuration. Interestingly, the polarization of bilayer β-MX shows a periodic variation with the change of X atoms, where the charge transfer is found to play an important role. Furthermore, both strain and multilayer stacking are found to be able to effectively modulate the polarization. With those structures, field-effect transistors (FETs) are constructed, and their performances are found to satisfy the International Technology Roadmap for Semiconductors (ITRS) requirements for the year 2028. Moreover, four kinds of logic operators are proposed and also demonstrated to operate quite well, showing great application potential. We believe our findings will be quite beneficial for the development of sliding ferroelectrics.
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