Aza-Diphosphazenanes: Inorganic Cyclohexane-like Connectors with Stereochemically Tunable Exit Vectors for Molecular and Macromolecular Chemistry.

• Tác giả: Joseph Bedard, S S Chitnis, Tanner George, Michael A Land, Jason D Masuda
• Ngôn ngữ: eng
• Ký hiệu phân loại: 616.2 Diseases of respiratory system
• Thông tin xuất bản: Germany : Angewandte Chemie (International ed. in English) , 2025
• Bộ sưu tập: NCBI
• ID: 753789

Tóm tắt

Molecules that place functional groups at well-defined angular and radial separations are valued as connectors in synthetic chemistry. Examples include rigid, polyvalent arenes and bicyclic compounds featuring strong C─C or C─H bonds. Aliphatic rings are rare in this context due to the challenge of stereochemical control over C─H functionalization. Here we investigate inorganic cyclohexane-like P