Synthetic alumosilicates are used in many industrial applications, and the synthesis of clay minerals under different conditions allows us to understand the conditions of their formation. This study examined the impact of varying silica precursors, pH conditions and synthesis durations. Synthetic kaolinite group mineral analogues were investigated by X-ray diffraction, scanning electron microscopy and infrared spectroscopy. Additionally, the crystallinity index was calculated. The impact of using different silica sources on the structural features of synthetic kaolinite group analogues was revealed. The use of a Nanosil precursor resulted in the formation of highly crystalline kaolinite. The most significant alterations in the course of synthesis were observed at different pH values. The formation of various synthetic analogues of minerals from the kaolinite group was observed: at a high pH, the formation of halloysite with a small admixture of kaolinite was observed. Conversely, the synthesis resulted in the formation of ordered kaolinite at a low pH. The crystallinity index of the resulting synthesized kaolinite analogues rises as the synthesis duration increases, while the quantity of non-crystallized material decreases. The changes in the crystallinity of kaolinite when using different silica precursors are related to the different homogenization of the material that occurs at the stage of alumosilica gel formation.