Processing lignin into nanoparticles (LNPs) offers a promising utilization strategy
however, its structural and molecular weight heterogeneity poses challenges in the formation of uniform LNPs. In this study, industrial kraft lignin was fractionated in stepwise molecular weight (Mw) from low to high and from which LNPs were fabricated via antisolvent precipitation. The results showed that lignin with high Mw benefits the formation of uniform and smaller-sized LNPs. Particularly, the lignin fraction with Mw of 2016 g·mol