Quantitative identification of melamine flame retardant in polyolefins with hyperspectral imaging and machine learning.

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Tác giả: Georgiana Amariei, Martin Lahn Henriksen, Mogens Hinge, Pernille Klarskov, Frederik Sprotte Reese

Ngôn ngữ: eng

Ký hiệu phân loại: 070.48346 Journalism

Thông tin xuất bản: England : Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 96553

Non-halogenated flame-retardant Melamine (MEL), an alternative to toxic halogenated flame retardants, has been recognized as a substance of very high concern by the ECHA. Therefore, identifying MEL in plastic waste is essential for ensuring safe handling and recycling. This study presents industrial in-line quantitative identification techniques for MEL in low-density polyethylene (LDPE) and polypropylene (PP) via short-waved infrared (SWIR) hyperspectral imaging combined with machine learning. LDPE and PP samples with varying MEL loadings were compounded and characterized through elemental analysis, ATR-FTIR, TGA, and DSC. Regression on the SWIR band area ratio and principal component one was applied to the SWIR spectra to compile predictive models. The models performed equally well, demonstrating a strong correlation between measured and predicted MEL concentrations. The model based on SWIR band area ratio ranged from 0.8 to 29.8 wt% MEL in LDPE (R
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