Passive sampling methods can provide valuable insights for monitoring hydrophobic organic compounds (HOCs) in aquatic environments. As the list of target HOCs expands, there is an increasing demand for passive samplers that can detect a broader range of these compounds. This study aimed to assess the efficacy of a three-layer co-extruded polyethylene/ethylene vinyl acetate (TLC-EVA) film alongside three existing materials (polyethylene (PE), polydimethylsiloxane (PDMS), and poly(methyl methacrylate) (PMMA)) for passive sampling of carbazole and five halogenated carbazoles (PHCZs), a group of dioxin-like chemicals, in water. The films were calibrated through batch experiments to determine the partition coefficients between the polymer and water (K